Drizzle oil over top of shrimp in a medium bowl. Stir to coat shrimp evenly.
Combine Sseasoning and ancho chile pepper in a small bowl. Sprinkle over top of shrimp and stir so seasoning coats shrimp evenly.
Skewer shrimp and grill over medium-high heat 3 to 4 minutes until shrimp turn pink and firm. Serve over rice.